三维电极电化学法处理聚苯硫醚废水研究

采用三维电极电化学方法对合成PPS废水进行处理,主要通过单因素试验和正交试验考察了初始pH、电极电流、极板间距、曝气强度、电解时间对于该PPS废水CODCr去除效果的影响,并在最佳条件下测试实验效果。结果表明:当在pH=8,电解电流为1 A,极板间距为8 cm,曝气强度为0.8 L/min,以8 g/L Na2SO4作为支持电解质电解100 min时,废水CODCr去除率可以达到54.3%。由正交试验得出影响CODCr去除率各因素的主次关系为:电极电流初始pH极板间距曝气强度电解时间。这充分说明三维电极法处理PPS废水是行之有效的方法,值得进一步研究。     

电感耦合发射光谱测煤灰中的元素

本文用三标准试样法来做校正曲线,用电感耦合离子发射光谱来测煤灰中Si、Al、Fe、Ca、Mg、Ti、S、P,这种方法方便快捷,准确度高,能同时测多种元素,每种元素的线性相关系数都大于0.999。     

树脂三维溶解度参数重叠率对涂层梯度化过程的影响研究

用溶剂匹配法测定了环氧树脂和有机硅改性丙烯酸树脂的三维溶解度参数,并研究了这两种树脂的溶解度参数重叠率对涂层形成梯度化的影响。该方法可为底面合一涂料的研发提供理论依据。     

Palladium‐Catalyzed Three‐Component Reaction of 3‐(Tri‐n‐ butylstannyl)allyl Acetates,Aldehydes, and Triorganoboranes: An Alternative to the Carbonyl Allylation Using α,γ‐Substituted Allylic Tin Reagents

A three‐component reaction of 3‐(tri‐n‐butylstannyl)allyl acetates, aldehydes, and triorganoboranes in the presence of a palladium‐Xantphos catalyst system predominately gave (E)‐anti‐homoallylic alcohols with high diastereoselectivity and good to high levels of alkene stereocontrol. An efficient chirality transfer was observed when an enantioenriched substrate was employed. The reaction was initiated by the formation of an allylic gem‐palladium/stannyl intermediate, which subsequently underwent allylation of the aldehyde by an allyltributyltin followed by a coupling reaction of the in‐situ‐generated (E)‐vinylpalladium acetate with the triorganoborane.

     

Intermittently Administered Parathyroid Hormone [1–34] Promotes Tendon-Bone Healing in a Rat Model

The objective of this study was to investigate whether intermittent administration of parathyroid hormone [1–34] (PTH[1–34]) promotes tendon-bone healing after anterior cruciate ligament (ACL) reconstruction in vivo. A rat model of ACL reconstruction with autograft was established at the left hind leg. Every day, injections of 60 μg PTH[1–34]/kg subcutaneously were given to the PTH group rats (n = 10) for four weeks, and the controls (n = 10) received saline. The tendon-bone healing process was evaluated by micro-CT, biomechanical test, histological and immunohistochemical analyses. The effects of PTH[1–34] on serum chemistry, bone microarchitecture and expression of the PTH receptor (PTH1R) and osteocalcin were determined. Administration of PTH[1–34] significantly increased serum levels of calcium, alkaline phosphatase (AP), osteocalcin and tartrate-resistant acid phosphatase (TRAP). The expression of PTH1R on both osteocytes and chondrocyte-like cells at the tendon-bone interface was increased in the PTH group. PTH[1–34] also enhanced the thickness and microarchitecture of trabecular bone according to the micro-CT analysis. The results imply that systematically intermittent administration of PTH[1–34] promotes tendon-bone healing at an early stage via up-regulated PTH1R. This method may enable a new strategy for the promotion of tendon-bone healing after ACL reconstruction.     

基于量纲分析的气力输送压降模型研究

量纲分析法是建立数学计算模型的一种重要的方法。以实验室气力输送数据为基础,结合量纲分析法,建立了管道压降计算准数关联式,同时将计算结果与实验数据进行对比分析,实验值与计算值总体变化趋势基本相同,偏差较小,并对其中误差相对较大的公式进行了修正,所得准数关联式对化工气力输送中压降的估算具有实际意义。     

ASP三元组分的残留对破乳过程动力学参数的影响

针对单一组分及ASP三元组分存在的两种不同乳液体系,以排液时间td、半生命期t1/2及破裂速率常数k为考核指标,采用单滴法研究了原油采出液中的残留组分聚合物、碱及表面活性剂的含量对破乳过程动力学参数的影响。结果表明:ASP三元组分的残留对动力学参数的影响呈现出一定的规律,其中,聚合物是使三元复合驱油体系破乳难度增大的主要因素,在含聚合物的乳液体系中,破裂速率常数比含碱和含表面活性剂体系小一个数量级,而碱与表面活性剂对破乳的影响与这两种组分的残留量有关。     

纵向通风下隧道长度对临界风速的影响分析

临界风速可有效控制烟气蔓延,是隧道防灾通风重要参数。为分析隧道长度对临界风速的影响,采用量纲分析法构建临界风速与隧道长度关系公式,并分别在5 MW和30 MW火源热释放速率下,对不同长度隧道的火灾进行数值模拟以量化研究隧道长度对临界风速的影响。结果表明,隧道长度对临界风速具有影响,且不同火源释放速率时影响也有所不同:无量纲火源热释放速率小于0.15时,临界风速随隧道长度增大呈现1/41次方增长关系;无量纲火源热释放速率高于0.15时,临界风速随隧道长度增大呈现1/25次方增长关系。进而建立了考虑隧道长度的无量纲临界风速计算公式。     

三光束光内同轴送丝激光熔覆成形新方法研究

目的研究"三光束光内同轴送丝"激光熔覆新方法以及单向、多向单道熔覆成形效果。方法采用光线追迹法分析了三光束光斑几何特性,运用TracePro分析了光斑能量分布。利用研制的三光束光内送丝装置进行了单向以及多向单道熔覆实验,对其展开成形表面质量以及单道熔覆层的组织和硬度分析。结果 "三光束光内同轴送丝"激光熔覆新方法可以将原始圆形激光束整形为周向均匀分布的三个扇形光斑,三个光斑光通量均沿着z轴方向呈"尖顶状"分布,丝材能够被三个光斑均匀包裹。基材和丝材采用不锈钢304材料,丝材线径为0.8 mm,负离焦量为2.5 mm,激光功率为1500 W,扫描速度为3.5 mm/s,送丝速度为20.5 mm/s,展开单向和多向单道熔覆成形测试,丝材熔化充分,熔覆层表面均匀平滑。熔覆层形貌和质量基本不受扫描方向的影响。单道熔覆层和基体结合良好,组织整体比较细密,无气孔和裂纹等缺陷,熔覆层底部到顶部晶粒形态主要为树枝晶、柱状晶、胞状晶和树枝晶,熔覆层组织为铁素体δ和奥氏体γ,凝固模式为FA模式,熔覆层底部到顶部铁素体δ的主要形态为板条状铁素体、蠕虫状铁素体、骨架状铁素体和板条状铁素体。熔覆层的平均硬度(228HV)明显高于基材硬度,熔覆层底部到顶部的硬度过渡平稳,不存在明显软化区,组织整体比较细小致密,晶粒分布均匀。结论 "三光束光内同轴送丝"激光熔覆新方法可以实现光、丝耦合,基材和丝材采用不锈钢304材料,选择合理的工艺参数,可以获得理想的单向以及多向单道熔覆成形效果。     

Enhancing the seismic performance of mid‐rise wood‐frame buildings with rigid spine columns

Wood‐frame buildings (WFBs) are the most commonly used structural systems for residential applications in North America. Past researches have shown that WFBs are susceptible to soft‐story mechanisms. In this study, a simple, efficient, and economical retrofit strategy, which utilizes continuous pinned‐supported rigid spine columns (RSCs) over the height of the building, is proposed. The retrofit aims to provide uniform deformation through the height of the building to prevent soft‐story mechanisms. This retrofit strategy was applied to a six‐story WFB located in Vancouver, British Columbia, Canada. A three‐dimensional nonlinear finite element model of the prototype building was developed using OpenSees. A comprehensive parametric study was conducted to identify the most economical RSC design. Seismic performance of the prototype building, with and without the most economical RSC design, was assessed through extensive nonlinear time history analyses. Results showed that the proposed retrofit strategy can effectively improve the seismic behavior of WFBs to prevent soft‐story mechanisms.